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Poster

WEB Structural and Magnetic Characterization of Iron Oxide Nanoparticles upon Chemical Lithiation

Friday (28.02.2020)
16:48 - 16:48 Poster Room
Part of:
Line-Up:
- Poster *web*Investigations of Medieval Zwischgold Samples by means of Transmission Electron Microscopy 1 Dr.-Ing. Julian Müller
- Poster *web*Evolution of bimodal L12 (γ') phase distribution and its effect on mechanical properties in nickel-based alloy 718Plus 1 Barun Bharadwaj Dash
- Poster *web*The effect of heat-treatment on micro structure and texture evolution in Ti-6Al-4V alloy and its effect on room temperature tensile properties and deformation mechanism 1 Shubhashis Dixit
- Poster *web*Benefits of evaluating coatings in real marine enviroment 1 Dipl.-Ing. Aiala Urbegain Garate
- Poster *web*Agglomeration of gold nanoparticles under microgravity conditions 1 Andrea Pyttlik
- Poster *web*Corrosion resistance of a Ni-based brazing alloy in a marine atmospheric exposure 1 Dipl.-Ing. Aiala Urbegain Garate
- Poster *web*Modelling of copper particle – copper wall collision at high velocities 1 Giedrius Jocbalis
- Poster *web*Impact of Strain Tensor on the Microstructure Evolution of Al-Sc-Zr-based Alloy 1 Bengü Tas Kavakbasi
- Poster *web*Template assisted synthesis of mesoporous Pt thin films and their use as electrocatalyst for the oxidation of glycerol 1 Ph.D. Athira Anil
- Poster *web*Structural and Magnetic Characterization of Iron Oxide Nanoparticles upon Chemical Lithiation 1 Seda Ulusoy
- Poster *web*Correlation between electrical and mechanical properties of silver nanowire electrodes studied by complementary in situ microscopy techniques 1 Marco Moninger
- Poster *web*Crack process evaluation in carbon fibre reinforced polymers aged by thermal cycling 1 Prof. Dr.-Ing. Fernando Lasagni

Session -C: Characterization
Belongs to:
Topic X: Poster Session


The spinel transition metal oxide Fe3O4 (magnetite) is an interesting candidate for electrode material in lithium ion batteries as it can store up to eight Li ions per formula unit, which leads to a high theoretical capacity of 926 mAh/g [1] Also, it has a low cost, high abundance and low toxicity [2]. However, the densely packed inverse spinel structure of magnetite causes solid-state mass transfer resistances that leads to poor active material utilization [3]. Therefore, the use of nanoscale is crucial to investigate as it will provide larger surface area/volume ratios that will give more pathways and reduction of path length for Li-ion movement [4]. Here, in this study, we explore chemical lithiation of nanosized magnetite particles at different sizes with different degrees of lithiation. We have used synchrotron X-ray diffraction to understand the structural changes as a function of degree of lithiation. Moreover, the lithiation changes the magnetic state of magnetite from ferrimagnetic to antiferromagnetic which enables probing the amount of lithiation using magnetometry.

 

Speaker:
Seda Ulusoy
Uppsala University
Additional Authors:
  • Alejandro Gomez Roca
    Catalan Institute of Nanoscience and Nanotechnology (ICN2)
  • Josep Nogues
    Catalan Institute of Nanoscience and Nanotechnology (ICN2)
  • Peter Svedlindh
    Uppsala University
  • Germán Salazar-Alvarez
    Uppsala University